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Integrated Chemical Process: One‐Pot Double Elimination Method for Acetylenes
Author(s) -
Orita Akihiro,
Yoshioka Naonori,
Struwe Petra,
Braier Arnold,
Beckmann Anke,
Otera Junzo
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990401)5:4<1355::aid-chem1355>3.0.co;2-0
Subject(s) - adduct , aldehyde , sulfone , chemistry , process (computing) , combinatorial chemistry , organic chemistry , computer science , catalysis , operating system
A novel one‐pot process for the synthesis of acetylenes is described that integrates the addition of an α‐anion of sulfone to aldehyde, the trapping of the resulting adduct to incorporate a leaving group, and the double elimination of this intermediate.