Premium
Reactions of Bare FeO + with Element Hydrides EH n (E=C, N, O, F, Si, P, S, Cl)
Author(s) -
Brönstrup Mark,
Schröder Detlef,
Schwarz Helmut
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990401)5:4<1176::aid-chem1176>3.0.co;2-2
Subject(s) - dehydrogenation , fourier transform ion cyclotron resonance , chemistry , ion , atom (system on chip) , analytical chemistry (journal) , mass spectrometry , inorganic chemistry , organic chemistry , catalysis , chromatography , computer science , embedded system
New mechanistic insight into basic reactions of FeO + and FeOH + is obtained by studying the transformations of these ions with the element hydrides CH 4 , NH 3 , H 2 O, SiH 4 , PH 3 , H 2 S, and HCl in a Fourier transform–ion cyclotron resonance (FT–ICR) mass spectrometer. The reaction channels can be classified into four different types: H . abstraction (a), dehydration (b), O‐atom transfer (c), and dehydrogenation (d), as depicted.