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Wagner–Meerwein Rearrangements in the Gas Phase: Deuterium Isotope Effects on Acid‐Induced Dissociation of Optically Active Phenylpropanols
Author(s) -
Speranza Maurizio,
Filippi Antonello
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990301)5:3<845::aid-chem845>3.0.co;2-8
Subject(s) - deuterium , kinetic isotope effect , chemistry , dissociation (chemistry) , protonation , gas phase , primary (astronomy) , kinetic energy , propanol , photochemistry , organic chemistry , ion , physics , quantum mechanics , astronomy , methanol
The combined analysis of the primary and secondary deuterium kinetic effects and of the activation parameters for water loss from O‐protonated ( S )‐1‐phenyl‐2‐propanol and ( S )‐2‐phenyl‐1‐propanol in the gas phase provides detailed information on the relevant transition states.