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Metal Iodides in Polyiodide Networks—The Structural Chemistry of Complex Gold Iodides with Excess Iodine
Author(s) -
Svensson Per H.,
Rosdahl Jan,
Kloo Lars
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990104)5:1<305::aid-chem305>3.0.co;2-8
Subject(s) - iodine , chemistry , metal , inorganic chemistry , iodine compounds , organic chemistry
The addition of metal iodides to polyiodides results in a competition between donor and acceptors in the system, and as a consequence the anionic networks can be modified in a controlled way. The inclusion of complex gold iodides into (R 3 S)I x polyiodides results in the compounds (Et 3 S)[AuI 4 ]⋅2 I 2 ( 1 ) and (Me 3 S) 2 [AuI 4 ][I 3 ] ( 2 ).