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The Effect of High Pressure on the Diastereoselectivity of Intermolecular All‐Carbon Diels–Alder Reactions
Author(s) -
Tietze Lutz F.,
Henrich Marielouise,
Niklaus Anja,
Buback Michael
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990104)5:1<297::aid-chem297>3.0.co;2-5
Subject(s) - intermolecular force , adduct , chemistry , diels–alder reaction , high pressure , carbon fibers , alder , organic chemistry , medicinal chemistry , stereochemistry , catalysis , materials science , botany , biology , molecule , thermodynamics , physics , composite number , composite material
Abstract Increased pressure favours the cis adducts in the cyclization of phenylbutadienes 1 with dicyanoethylenes 2 to give cyclohexenes.