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Metal Reactivity on Oxo Surfaces Modeled by Calix[4]arenes: Metal‐Driven Reactions in an Oxo‐Quasiplanar Environment
Author(s) -
Floriani Carlo
Publication year - 1999
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19990104)5:1<19::aid-chem19>3.0.co;2-7
Subject(s) - reactivity (psychology) , metal , cleavage (geology) , transition metal , olefin fiber , chemistry , photochemistry , nitride , polymer chemistry , materials science , organic chemistry , catalysis , medicine , alternative medicine , pathology , fracture (geology) , composite material , layer (electronics)
Olefin rearrangements to alkylidynes and alkylidenes driven by acids, bases, or light, and dinitrogen cleavage to nitride (depicted here) are all possible with the aid of transition metals anchored to a preorganised oxo surface, illustrated by calix[4]arene anions.