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Donor–π‐Acceptor Species Derived from Functionalised 1,3‐Dithiol‐2‐ylidene Anthracene Donor Units Exhibiting Photoinduced Electron Transfer Properties: Spectroscopic, Electrochemical, X‐Ray Crystallographic and Theoretical Studies
Author(s) -
Batsanov Andrei S.,
Bryce Martin R.,
Coffin Malcolm A.,
Green Andrew,
Hester Ronald E.,
Howard Judith A. K.,
Lednev Igor K.,
Martín Nazario,
Moore Adrian J.,
Moore John N.,
Ortí Enrique,
Sánchez Luis,
Savirón María,
Viruela Pedro M.,
Viruela Rafael,
Ye TianQing
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19981204)4:12<2580::aid-chem2580>3.0.co;2-8
Subject(s) - intramolecular force , anthracene , acceptor , electrochemistry , dithiol , steric effects , chemistry , crystallography , electron transfer , electron acceptor , ab initio , ab initio quantum chemistry methods , crystal structure , single crystal , photochemistry , molecule , stereochemistry , organic chemistry , electrode , physics , condensed matter physics
Steric interactions between the anthraquinoid core and the 1,3‐dithiole and dicyanomethylene groups play a key role in determining the physical properties of system 1 . The intramolecular charge transfer properties of this donor–π‐acceptor species have been explored and cyclic voltammetric data, X‐ray crystal structures and ab initio calculations are also reported.