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Tripod–Tripod Coupling of Triazides with Triphosphanes. The Synthesis, Characterization, and Stability in Solution of New Cage Compounds: Chiral Macrobicyclic Triphosphazides
Author(s) -
Alajarín Mateo,
LópezLázaro Antonia,
Vidal Angel,
Berná José
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19981204)4:12<2558::aid-chem2558>3.0.co;2-3
Subject(s) - tripod (photography) , cage , topology (electrical circuits) , chemistry , materials science , stereochemistry , physics , mathematics , engineering , structural engineering , combinatorics , optics
Rare intracyclic PN 3 units of Z configuration are present in the three arms of the unprecedented, rigid macrobicycles of propellerlike topology ( 1 ) formed by self‐assembly of triazides and CH 3 C(CH 2 PPh 2 ) 3 (triphos).