Premium
Evidence for the Non‐Concerted Addition of Difluorovinylidene to Acetylenes
Author(s) -
Kötting Carsten,
Sander Wolfram,
Senzlober Michael
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19981102)4:11<2360::aid-chem2360>3.0.co;2-y
Subject(s) - acetylene , irradiation , chemistry , materials science , physics , nuclear physics , organic chemistry
The addition of difluorovinylidene (1) to difluoroacetylene (2) at cryogenic temperatures leads to the allenylcarbene 3 . Subsequent irradiation results in the expected methylenecyclopropene 4 . Furthermore the addition of difluorovinylidene to acetylene is investigated.