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C−H Bond Activation of Benzene and Cyclic Ethers by TpIr III Species
Author(s) -
GutiérrezPuebla Enrique,
Monge Ángeles,
Nicasio M. Carmen,
Pérez Pedro J.,
Poveda Manuel L.,
Carmona Ernesto
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19981102)4:11<2225::aid-chem2225>3.0.co;2-i
Subject(s) - benzene , chemistry , hydride , carbene , medicinal chemistry , alkyl , derivative (finance) , ligand (biochemistry) , polymer chemistry , stereochemistry , organic chemistry , catalysis , hydrogen , biochemistry , receptor , financial economics , economics
An unusual Fischer carbene derivative that, in addition, contains an alkyl and a hydride ligand is obtained by C−H bond activation of THF by the hydride–vinyl species [Tp Me2 IrH(CHCH 2 ) (C 2 H 4 )]. This complex is also capable of activating the C−H bonds of benzene to give remarkably stable Ir III –N2 complexes (see illustration).