Premium
Regioselective Gold Complexation within the Cascade Structure of Phosphorus‐Containing Dendrimers
Author(s) -
Larré Christophe,
Donnadieu Bruno,
Caminade AnneMarie,
Majoral JeanPierre
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19981002)4:10<2031::aid-chem2031>3.0.co;2-j
Subject(s) - dendrimer , regioselectivity , cascade , phosphorus , chemistry , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , chromatography
The selective incorporation of gold , when and where desired, within dendritic and multidendritic macromolecules can be accomplished by means of complexation on internal PNPNPS, PNPS, and PR 2 groups; up to 90 AuCl moieties can be grafted into the internal layers of a multidendritic giant molecule (see picture).