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Generating Structural Motifs between Three‐Dimensional Solids and Discrete Species Based on the {CuNCS} Unit: (PPh 4 )[(ReS 4 )Cu 2 (NCS) 2 ], (NEt 4 ) 2 [(ReS 4 )Cu 3 (NCS) 4 ], and (PPh 4 ) 2 [(ReS 4 ) 2 Cu 2 (NCS) 2 ]
Author(s) -
Müller Achim,
Hildebrand Achim,
Krickemeyer Erich,
Khan Mohammed Isaque,
Penk Michael,
Bögge Hartmut,
Sécheresse Francis
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19981002)4:10<1932::aid-chem1932>3.0.co;2-z
Subject(s) - crystallography , chemistry , unit (ring theory) , structural motif , stereochemistry , mathematics , biochemistry , mathematics education
Novel and unusual structural motifs are yielded from the reaction of (PPh 4 )ReS 4 or (NEt 4 )ReS 4 with CuNCS (in different solvents and with different relative amounts of reactants). In one example (right) one Cu(NCS) 2 and two Cu(NCS) units are linked by ReS 4 − groups leading to twelve‐ and sixteen‐membered rings alternately arranged in a linear strand.