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The First Theoretical and Experimental Proof of Polythiocarbamatozinc( II ) Complexes, Catalysts for Sulfur Vulcanization
Author(s) -
Nieuwenhuizen Peter J.,
Ehlers Andreas W.,
Hofstraat Johannes W.,
Janse Sander R.,
Nielen Michel W. F.,
Reedijk Jan,
Baerends EvertJan
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980904)4:9<1816::aid-chem1816>3.0.co;2-z
Subject(s) - vulcanization , sulfur , catalysis , mass spectrometry , ionization , desorption , chemistry , computational chemistry , inorganic chemistry , organic chemistry , ion , natural rubber , adsorption , chromatography
Polythiocarbamatozinc( II ) complexes such as 1 , which were suggested as early as 1921, have always defied science. Now density functional calculations and laser‐desorption ionization mass spectrometry provide proof for the existence of these inferred catalysts for sulfur vulcanization.