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The Synthesis of Some Phthalocyanines and Napthalocyanines Derived from Sterically Hindered Phenols
Author(s) -
Brewis Matthew,
Clarkson Guy J.,
Humberstone Paul,
Makhseed Saad,
McKeown Neil B.
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980904)4:9<1633::aid-chem1633>3.0.co;2-o
Subject(s) - steric effects , phenols , chemistry , combinatorial chemistry , organic chemistry
A nucleophilic aromatic substitution reaction between a sterically hindered phenol and 4‐nitrophthalonitrile, 3‐nitrophthalonitrile or 6‐fluoro‐2,3‐napthalonitrile has been used to prepare precursors for the synthesis of a number of phthalocyanines, such as 1 , and naphthalocyanines bearing bulky substituents.