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Interaction of Alkali Metal Cations (Li + –Cs + ) with Glycine in the Gas Phase: A Theoretical Study
Author(s) -
Hoyau Sophie,
Ohanessian Gilles
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980807)4:8<1561::aid-chem1561>3.0.co;2-z
Subject(s) - alkali metal , chemistry , glycine , gas phase , sodium , inorganic chemistry , phase (matter) , metal , organic chemistry , amino acid , biochemistry
The interaction of gaseous glycine with alkali cations (Li + –Cs + ) involves three low‐energy isomers (below), the relative energies of which depend upon the cation. Interconversion between these structures involves at most 20.4 kcal mol −1 for the sodium complex.