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Molecular Structure and Dynamics of 1,3‐Distanna‐2‐Platina[3]Ferrocenophanes
Author(s) -
Herberhold Max,
Steffl Udo,
Milius Wolfgang,
Wrackmeyer Bernd
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980615)4:6<1027::aid-chem1027>3.0.co;2-3
Subject(s) - chemistry , platinum , chelation , molecule , stereochemistry , molecular dynamics , catalysis , medicinal chemistry , combinatorial chemistry , computational chemistry , organic chemistry
The active intermediates in the Pt( 0 )‐catalyzed distannation of alkynes are bis(stannyl)bis(phosphane)platinum( II ) complexes. In the present work trimethylstannyl platinum complexes and derivatives of platina[3]ferrocenophanes with various chelating diphosphane ligands (e.g. 1 ) have been investigated in order to obtain further information on the structure and the molecular dynamics of such molecules.