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Unusual Stepwise Assembly and Molecular Growth: [H 14 Mo 37 O 112 ] 14− and [H 3 Mo 57 V 6 (NO) 6 O 189 (H 2 O) 12 (MoO) 6 ] 21−
Author(s) -
Müller Achim,
Meyer Jochen,
Krickemeyer Erich,
Beugholt Christian,
Bögge Hartmut,
Peters Frank,
Schmidtmann Marc,
Kögerler Paul,
Koop Michael James
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980615)4:6<1000::aid-chem1000>3.0.co;2-c
Subject(s) - materials science , crystallography , chemistry
A type of molecular symmetry breaking or unusual stepwise molecular growth processes, exemplified below, lead to the cluster anions [H 14 Mo 37 O 112 ] 14− and [H 3 Mo 63 V 6 (NO) 6 O 195 (H 2 O) 12 ] 21− . The processes have model characteristics for the metal release and uptake of metal storage proteins in biological systems.