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Cyclophanes and [2]Catenanes as Ligands for Transition Metal Complexes: Synthesis, Structure, Absorption Spectra, and Excited State and Electrochemical Properties
Author(s) -
Ashton Peter R.,
Balzani Vincenzo,
Credi Alberto,
Kocian Oldrich,
Pasini Dario,
Prodi Luca,
Spencer Neil,
Stoddart J. Fraser,
Tolley Malcolm S.,
Venturi Margherita,
White Andrew J. P.,
Williams David J.
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980416)4:4<590::aid-chem590>3.0.co;2-c
Subject(s) - rhenium , ruthenium , catenane , transition metal , electrochemistry , metal , chemistry , photochemistry , copper , crystallography , polymer chemistry , combinatorial chemistry , stereochemistry , inorganic chemistry , molecule , organic chemistry , catalysis , electrode
Two tetracationic cyclophanes and two [2]catenanes containing paraquat‐type units together with one or two transition metal chelating 2,2′‐bipyridyl moieties have been synthesized. The metal‐binding units have been used to generate novel mono‐ and binuclear ruthenium( II ), rhenium( I ), silver( I ) (right), and copper( I ) complexes.