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Synthesis of Fucosyl Saccharides under Neutral Conditions in Solutions of Lithium Perchlorate in Dichloromethane
Author(s) -
Schmid Uschi,
Waldmann Herbert
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980310)4:3<494::aid-chem494>3.0.co;2-8
Subject(s) - dichloromethane , perchlorate , glycosyl , chemistry , lithium perchlorate , anomer , lithium (medication) , organic chemistry , solvent , ion , biology , endocrinology , electrolyte , electrode
The α ‐anomer of the human blood group H determinant is one of the fucosyl saccharides that can be built up under very mild conditions by employing fucosyl fluorides as glycosyl donors in 0.07 M LiClO 4 /CH 2 Cl 2 as reaction medium (below).