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Self‐Assembly of Porphyrin Arrays by Hydrogen Bonding in the Solid State: An Orthogonal Porphyrin–Bisresorcinol System
Author(s) -
Kobayashi Kenji,
Koyanagi Masayuki,
Endo Ken,
Masuda Hideki,
Aoyama Yasuhiro
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980310)4:3<417::aid-chem417>3.0.co;2-s
Subject(s) - porphyrin , hydrogen bond , orthogonality , molecule , materials science , derivative (finance) , solid state , self assembly , metal , crystallography , photochemistry , chemistry , nanotechnology , organic chemistry , geometry , mathematics , financial economics , economics , metallurgy
The orthogonality strategy provides a logical design principle for aromatic columns and microporosity in molecular crystals. An orthogonal porphyrin–bisresorcinol derivative 1 forms an extensive hydrogen‐bonded network in which the porphyrin rings are forced into columns; the large cavities left can incorporate guest molecules by hydrogen‐bonding or metal‐coordination interactions.