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Dianions and Tetraanions of Bowl‐Shaped Fullerene Fragments Dibenzo[ a,g ]corannulene and Dibenzo[ a,g ]cyclopenta[ kl ]corannulene
Author(s) -
Weitz Amir,
Shabtai Elad,
Rabinovitz Mordecai,
Bratcher Matthew S.,
McComas Casey C.,
Best Michael D.,
Scott Lawrence T.
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(19980210)4:2<234::aid-chem234>3.0.co;2-5
Subject(s) - corannulene , fullerene , chemistry , ring (chemistry) , alkali metal , computational chemistry , stereochemistry , polymer chemistry , organic chemistry
The fullerene fragment 1 (C 28 H 14 ) gives a paratropic dianion and a diatropic tetraanion on alkali metal reduction, whereas the C 30 H 14 hydrocarbon 2 , which contains just one more ring from the C 60 network, gives a diatropic dianion and a paratropic tetraanion.