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Liquid Crystalline Octahedral Iron( III ) Complexes with 1,4,7‐Tris[3,4‐bis(decyloxy)benzyl]‐1,4,7‐triazacyclononane: Thermal Characterization and Mössbauer Investigations of Bridging and Redox Behavior
Author(s) -
Walf G. Henning,
Benda Rüdiger,
Litterst F. Jochen,
Stebani Uwe,
Schmidt Steven,
Lattermann Günter
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(199801)4:1<93::aid-chem93>3.0.co;2-x
Subject(s) - mössbauer spectroscopy , redox , octahedron , crystallography , anhydrous , tris , materials science , chemistry , inorganic chemistry , crystal structure , organic chemistry , biochemistry
The bridging behavior and redox mechanisms of liquid crystalline octahedral iron( III ) complexes (such as the anhydrous complex below) were studied in detail by polarization microscopy, DSC, and Mössbauer spectroscopy. We gained great insight into the changes in molecular structure, and describe here a new type of magnetic short‐range order in liquid crystals.