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New Alkali Metal Primary Amide Ladder Structures Derived from t BuNH 2 : Building Cisoid and Transoid Ring Conformations into Ladder Frameworks
Author(s) -
Clegg William,
Henderson Kenneth W.,
Horsburgh Lynne,
Mackenzie Fiona M.,
Mulvey Robert E.
Publication year - 1998
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/(sici)1521-3765(199801)4:1<53::aid-chem53>3.0.co;2-4
Subject(s) - alkali metal , amide , lithium (medication) , ring (chemistry) , chemistry , derivative (finance) , sodium , crystal structure , crystallography , metal , primary (astronomy) , stereochemistry , physics , organic chemistry , medicine , astronomy , financial economics , economics , endocrinology
An unprecedented family of ladder compounds , each with a unique architecture and rung size, is completed by the crystal structures of a sodium and a mixed lithium–sodium derivative of tert ‐butylamine. This further illustrates that primary amines make excellent precursors for constructing novel alkali metal amide ladder structures.