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Preparation and Characterization of Yttrium–Titanium Citrate Complexes
Author(s) -
Getsova M. M.,
Todorovsky D. S.,
Arnaudov M. G.
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(200006)626:6<1488::aid-zaac1488>3.0.co;2-i
Subject(s) - yttrium , chemistry , bimetallic strip , titanium , nuclear chemistry , inorganic chemistry , deprotonation , metal , polymer chemistry , organic chemistry , oxide , ion
Yttrium, titanium, and yttrium‐titanium citrate complexes are synthesized in ethylene glycol medium at conditions similar to those used when the polymerized complex method (a version of the sol‐gel technology) is applied. The composition and IR, 1 H and 13 C NMR spectral characteristics of the isolated solid state complexes are studied. Proofs of the mixed metal nature of the bimetallic complexes are reported. The conditions of deprotonation of the alcoholic OH group of the citrate ligands are considered.