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The Structure of Hydrotris(imidazolyl)boratothallium(I) – the First Structurally Authenticated Tris(imidazolyl)borate Metal Complex
Author(s) -
Janiak Christoph,
Röhr Caroline,
Temizdemir Savaş
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(200006)626:6<1265::aid-zaac1265>3.0.co;2-f
Subject(s) - monoclinic crystal system , tris , crystallography , boron , thallium , chemistry , metal , ligand (biochemistry) , crystal structure , stereochemistry , inorganic chemistry , organic chemistry , receptor , biochemistry
The title compound crystallizes in the monoclinic space group P2 1 /n with a = 8.706(1), b = 9.192(1), c = 15.261(2) Å, β = 94.740(3)°, V = 1217.0(3) Å 3 , Z = 4, D calc = 2.278 g cm –3 . The tris(imidazolyl)borate ligand bridges between three thallium atoms. The structure consists of one‐dimensional twisted ladder‐like strands.