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Kristallstrukturen von Na 3 TiCl 6 und K 3 TiCl 6
Author(s) -
Hinz Dirk,
Gloger Thomas,
Meyer Gerd
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(200004)626:4<822::aid-zaac822>3.0.co;2-6
Subject(s) - monoclinic crystal system , crystallography , crystal structure , cryolite , halide , ternary operation , chemistry , molar ratio , materials science , inorganic chemistry , aluminium , biochemistry , organic chemistry , computer science , programming language , catalysis
Ternary Halides of the Type A 3 MX 6 . IX Crystal Structures of Na 3 TiCl 6 and K 3 TiCl 6 Light yellow single crystals of Na 3 TiCl 6 and K 3 TiCl 6 are obtained from the binary components, TiCl 3 and NaCl and KCl, respectively, in 1 : 3 molar ratios. Na 3 TiCl 6 crystallizes with the cryolite type of structure (monoclinic, P2 1 /n, Z = 2, a = 668,02(8), b = 709,13(6), c = 981,38(12) pm, β = 90,31(2)°) while K 3 TiCl 6 belongs to the K 3 MoCl 6 type of structure (monoclinic, P2 1 /c, Z = 4, a = 1261,6(2), b = 751,36(8), c = 1210,7(2) pm, β = 108,30(2)°).