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Molekülstruktur und thermische Stabilität des metallacyclischen Platin(II)‐Komplexes [Li(TMEDA)] 2 Pt(CH 2 CMe 2 CMe 2 CH 2 ) 2
Author(s) -
Wyrwa R.,
Fröhlich H.O.,
Görls H.
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(200004)626:4<819::aid-zaac819>3.0.co;2-j
Subject(s) - homoleptic , platinum , chemistry , thermal decomposition , thermal stability , crystallography , stereochemistry , metal , catalysis , organic chemistry
Molecular Structure and Thermal Stability of the Metallacyclic Platinum(II) Complex [Li(TMEDA)] 2 Pt(CH 2 CMe 2 CMe 2 CH 2 ) 2 The X‐ray investigation at the “ate‐complex” [Li(TMEDA)] 2 Pt(CH 2 CMe 2 CMe 2 CH 2 ) 2 ( 1 ) revealed a new structure type of homoleptic organometallic compounds of platinum(II). Differences of the molecular structure of the “ate‐complex” [Li(TMEDA)] 2 Pt(CH 2 CH 2 CH 2 CH 2 ) 2 ( 2 ) as well as similarities to the structure of the homologeous “ate‐complex” of nickel(II) [Li(TMEDA)] 2 Ni(CH 2 CMe 2 CMe 2 CH 2 ) 2 ( 3 ) are described. A possible mechanism of the thermal decomposition of the complex 1 is discussed.