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Ein neues Phosphorsulfid mit Adamantangerüst: δ‐P 4 S 7
Author(s) -
Nowottnick Heike,
Blachnik Roger
Publication year - 2000
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(200003)626:3<611::aid-zaac611>3.0.co;2-o
Subject(s) - adamantane , sulfur , chemistry , sulfide , triphenylphosphine , nuclear magnetic resonance spectroscopy , phosphorus , stereochemistry , organic chemistry , catalysis
A New Phosphorus Sulfide with Adamantane Structure: δ‐P 4 S 7 By sulfur abstraction from α‐P 4 S 9 /P 4 S 10 with triphenylphosphine a new phosphorus sulfide δ‐P 4 S 7 with adamantane skeleton and an additional sulfur in exo‐position was identified in CS 2 ‐solution by 31 P‐NMR spectroscopy. Product distribution and 31 P‐NMR parameter are given.