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Facile and Optimized Syntheses and Structures of Crystalline Molybdenum Blue Compounds Including one with an Interesting High Degree of Defects: Na 26 [Mo 142 O 432 (H 2 O) 58 H 14 ] · ca. 300 H 2 O and Na 16 [(MoO 3 ) 176 (H 2 O) 63 (CH 3 OH) 17 H 16 ] · ca. 600 H 2 O · ca. 6 CH 3 OH
Author(s) -
Müller Achim,
Beugholt Christian,
Koop Michael,
Das Samar K.,
Schmidtmann Marc,
Bögge Hartmut
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199912)625:12<1960::aid-zaac1960>3.0.co;2-a
Subject(s) - molybdenum , molybdenum blue , yield (engineering) , reactivity (psychology) , chemistry , degree (music) , cluster (spacecraft) , crystallography , materials science , inorganic chemistry , organic chemistry , metallurgy , physics , acoustics , medicine , alternative medicine , phosphate , pathology , computer science , programming language
The syntheses and structures of the two mixedvalence crystalline molybdenum blue compounds Na 26 [Mo 142 O 432 (H 2 O) 58 H 14 ] · ca. 300 H 2 O ( 1 ) (containing the maximal number of well defined defects which influence the overall structure and the reactivity of the anionic cluster) and Na 16 [(MoO 3 ) 176 (H 2 O) 63 (CH 3 OH) 17 H 16 ] · ca. 600 H 2 O · ca. 6 CH 3 OH ( 2 ) (obtained in an optimized high‐yield synthesis) are reported with reference to the critical conditions required for the isolation of corresponding crystalline materials.