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{Ph 2 (Carb)P}MCl 3 (M = Pd, Pt; Carb = 2,3‐dihydro‐1,3‐diisopropyl‐4,5dimethylimidazol‐2‐ylidene) – a Novel Cationic Phosphane Ligand [1]
Author(s) -
Kuhn Norbert,
Henkel Gerald,
Göhner Martin
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199909)625:9<1415::aid-zaac1415>3.0.co;2-3
Subject(s) - cationic polymerization , ligand (biochemistry) , chemistry , chloride , medicinal chemistry , salt (chemistry) , catalysis , organic chemistry , receptor , biochemistry
Abstract The phosphane ligand [Ph 2 (Carb)P] + forms neutral complexes {Ph 2 (Carb)P}MCl 3 (Carb = 2,3‐dihydro‐1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene; M = Pd, Pt) through the reaction of it's chloride salt with (PhCN) 2 MCl 2 ; the triarylphosphane type properties of the ligand are revealed by n.m.r. and structural data.