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Synthese und Kristallstruktur von [(PhCH 2 ) 2 GaF( t BuNH 2 )] 2 · 2 THF
Author(s) -
Kopp Mike R.,
Neumüller Bernhard
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199909)625:9<1413::aid-zaac1413>3.0.co;2-f
Subject(s) - adduct , crystal structure , chemistry , crystallography , molecule , organic chemistry
Synthesis and Crystal Structure of [(PhCH 2 ) 2 GaF( t BuNH 2 )] 2 · 2 THF (PhCH 2 ) 2 GaF reacts with t BuNH 2 to the adduct [(PhCH 2 ) 2 GaF( t BuNH 2 )] ( 1 ). 1 was characterized by NMR, IR and MS techniques. 1 can be recrystallized from THF forming crystals of [ 1 ] 2 · 2 THF. According to an X‐ray structure analysis [ 1 ] 2 · 2 THF consists of dimers of 1 formed by hydrogen bridges. The THF molecules are coordinated to [ 1 ] 2 by hydrogen bridges, too.