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Synthesis and Crystal Structure of a New Silver(I) Complex
Author(s) -
Adhami Forough,
Ghassemzadeh Mitra,
Heravi Majid M.,
Taeb Abas,
Neumüller Bernhard
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199909)625:9<1411::aid-zaac1411>3.0.co;2-r
Subject(s) - crystal structure , coordination sphere , crystallography , solid state , methanol , chemistry , triazine , elemental analysis , lattice (music) , infrared spectroscopy , inorganic chemistry , physics , polymer chemistry , organic chemistry , acoustics
The reaction of 4‐amino‐6‐methyl‐1,2,4‐triazine‐3(2 H)‐thione‐5‐one (AMTTO) with silver(I) nitrate in methanol gives the complex [Ag(AMTTO) 2 ]NO 3 ( 1 ). 1 was characterized by IR and 13 C NMR spectroscopy and by an X‐ray structure analysis [space group C2/c, Z = 4, lattice dimensions at –80 °C: a = 1306.7(2), b = 1139.0(2), c = 1089.2(1) pm, β = 94.54(1)°, R 1 = 0.0294]. The cation possesses a highly distorted linear coordination sphere in the solid state.