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Synthesis and Structure of [NbCl 3 (NPPh 2 Fc) 2 ]: The First Example of a Complex Containing a Redox‐functionalised Phosphaneiminato Ligand
Author(s) -
Siemeling Ulrich,
Stammler Anja,
Stammler HansGeorg,
Kuhnert Oliver
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199906)625:6<845::aid-zaac845>3.0.co;2-f
Subject(s) - redox , ligand (biochemistry) , niobium , chemistry , crystal structure , combinatorial chemistry , crystallography , polymer chemistry , stereochemistry , inorganic chemistry , organic chemistry , receptor , biochemistry
Reaction of Me 3 SiNPPh 2 Fc (Fc = ferrocenyl) with niobium pentachloride affords [NbCl 3 (NPPh 2 Fc) 2 ], whose redox‐functionalised phosphaneiminato ligands exhibit remarkably different bend angles at nitrogen according to a crystal structure analysis.