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The Reactions of Zn(CF 3 )Br · 2 CH 3 CN with Phenol, Pentafluorophenol, their Potassium and Ammonium Salts
Author(s) -
Pasenok Sergej V.,
Yagupolskii Yurii L.,
Tyrra Wieland,
Naumann Dieter
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199905)625:5<831::aid-zaac831>3.0.co;2-0
Subject(s) - chemistry , phenol , potassium , medicinal chemistry , tris , ether , ammonium , mass spectrum , nuclear chemistry , organic chemistry , ion , biochemistry
Triphenoxymethane, tris(pentafluorophenoxy)methane, phenyl(difluoromethyl)ethers, and tetrakis(pentafluorophenoxy)ethene were prepared via carbenoid reactions of Zn(CF 3 )Br · 2 CH 3 CN and the corresponding phenol or the potassium or ammonium salts in the presence of the auxiliary acid BF 3 · O(CH 3 ) 2 . The products were identified by their melting and boiling points and in part by their NMR and mass spectra as well as elemental analysis.