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Zweifach phosphonylierte Triphenylphosphane – neue Liganden mit ausgezeichneter Wasserlöslichkeit
Author(s) -
Kant Michael,
Bischoff Stefan
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199905)625:5<707::aid-zaac707>3.0.co;2-t
Subject(s) - diphosphonates , triphenylphosphine , phosphonate , solubility , chemistry , combinatorial chemistry , stereochemistry , organic chemistry , medicine , catalysis , bone resorption
Triphenylphosphine Diphosphonates – New Ligands with Excellent Water‐Solubility A highly selective method for the functionalization of triarylphosphines with phosphonate moieties has been developed. New ligands with excellent solubility in water, such as the previously unknown triphenylphosphine‐diphosphonates PhP[3‐C 6 H 4 –PO 3 Na 2 ] 2 and PhP[4‐C 6 H 4 –PO 3 Na 2 ] 2 , are accessible by this efficient synthesis route.