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Synthese und Kristallstruktur von iso ‐Butylimidogalliummethyl, [CH 3 Ga–NCH 2 CH(CH 3 ) 2 ] 6
Author(s) -
Schmid K.,
Niemeyer M.,
Weidlein J.
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199902)625:2<186::aid-zaac186>3.0.co;2-v
Subject(s) - crystal structure , raman spectroscopy , yield (engineering) , thermal decomposition , molecule , crystallography , molar ratio , hexagonal crystal system , chemistry , decomposition , materials science , organic chemistry , catalysis , physics , optics , metallurgy
Synthesis and X‐Ray Structure Determination of iso ‐Butylimido Galliummethyl, [CH 3 Ga–NCH 2 CH(CH 3 ) 2 ] 6 The thermal decomposition of [Me 2 Ga–N( i Bu)SnMe 3 ] 2 (prepared by the reaction of [Me 2 SnN i Bu] 3 with GaMe 3 in a 1:3 molar ratio) in an evacuated, sealed tube at 160°C forms [MeGaN i Bu] 6 in high yield and SnMe 4 . Mass, 1 H and 13 C NMR as well as some IR and Raman spectroscopic data are given and the crystal structure of this cage molecule with a hexagonal prismatic Ga 6 N 6 skeleton has been determined.