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[Cd(STrt) 3 ] – , ein homoleptischer Cadmiumkomplex mit dem sterisch anspruchsvollen Triphenylmethanthiolat‐Liganden
Author(s) -
Duhme AnneKathrin,
Strasdeit Henry
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199901)625:1<6::aid-zaac6>3.0.co;2-w
Subject(s) - homoleptic , steric effects , chemistry , tetrahydrofuran , ligand (biochemistry) , crystallography , trigonal crystal system , yield (engineering) , stereochemistry , crystal structure , metal , materials science , organic chemistry , biochemistry , receptor , solvent , metallurgy
[Cd(STrt) 3 ] – , a Homoleptic Cadmium Complex with the Sterically Demanding Triphenylmethanethiolate Ligand Crystalline [K(18‐crown‐6)(THF) 2 ][Cd(STrt) 3 ] · 2 THF ( 1 ) has been isolated in 77% yield from the reaction of CdCl 2 , KSTrt and 18‐crown‐6 in tetrahydrofuran (THF; Trt = triphenylmethyl). The Cd II ion of 1 exhibits a distorted trigonal coordination by three thiolate ligands (Cd–S 2.461(2)–2.518(2) Å, S–Cd–S 106.87(5)–135.20(5)°, Cd atom 0.24 Å above the S 3 plane).