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Synthese und Struktur von [Fe 6 (CO) 12 (TePh) 12 ]
Author(s) -
Bettenhausen Marco,
Fenske Dieter
Publication year - 1999
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199901)625:1<13::aid-zaac13>3.0.co;2-k
Subject(s) - crystal structure , chemistry , ring (chemistry) , crystallography , stereochemistry , trigonal crystal system , organic chemistry
Synthesis and Structure of [Fe 6 (CO) 12 (TePh) 12 ] The reaction of [Fe(CO) 4 (HgCl) 2 ] with PhTeSiMe 3 leads to the formation of red needles. [Fe 6 (CO) 12 (TePh) 12 ] was characterised by single crystal x‐ray structure analysis. In this compound each iron atom is coordinated octahedrally by four μ 2 ‐TePh groups and two terminal CO groups. The iron atoms form a six membered planar ring.