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Palladium(II)‐, Platin(II)‐, Ruthenium(II)‐, Rhodium(III)‐ und Iridium(III)‐Komplexe von Desoxyfructosazin
Author(s) -
Krawielitzki Stefan,
Beck Wolfgang
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - German
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199810)624:10<1718::aid-zaac1718>3.0.co;2-z
Subject(s) - rhodium , iridium , ruthenium , chemistry , palladium , pyrazine , platinum , medicinal chemistry , metal , derivative (finance) , stereochemistry , catalysis , organic chemistry , financial economics , economics
Das Pyrazinderivat Desoxyfructosazin(pz) liefert mit K 2 PtCl 4 sowie den chlorverbrückten Verbindungen [M(PR 3 )Cl 2 ] 2 (M = Pd, Pt), [(η 5 ‐C 5 Me 5 )MCl 2 ] 2 und [(η 6 ‐p‐Cymol)RuCl 2 ] 2 die wasserlöslichen Komplexe cis‐Cl 2 Pt(pz) 2 , (R 3 P)(Cl)M(pz)M(Cl)(PR 3 ) (M = Pd, Pt), (η 5 ‐C 5 Me 5 )(Cl) 2 M(pz)M(Cl) 2 (η 5 ‐C 5 Me 5 ) (M = Rh, Ir) und (η 6 ‐p‐Cymol)(Cl 2 )Ru(pz)Ru(Cl) 2 (η 6 ‐p‐Cymol).

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