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Kristallstruktur von [ZnH(NPMe 3 )] 4 , einem tetrameren Phosphaniminato‐Komplex des Zinks mit terminalen Hydrido‐Liganden
Author(s) -
Krieger Matthias,
Neumüller Bernhard,
Dehnicke Kurt
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199810)624:10<1563::aid-zaac1563>3.0.co;2-u
Subject(s) - crystal structure , crystallography , chemistry , molecule , stereochemistry , organic chemistry
Crystal Structure of [ZnH(NPMe 3 )] 4 , a Tetrameric Phosphoraneiminato Complex of Zinc with Terminal Hydrido Ligands The crystal structure of the title compound, which crystallizes as [ZnH(NPMe 3 )] 4 · 4 THF forming colourless, very reactive blocks, obtained by recrystallization from toluene, reveals discrete tetrameric molecules with heterocubane structure with almost undistorted Zn 4 N 4 cubic skeletons. The hydrido ligands assume terminal exocyclic positions with Zn–H bond lengths of 150 pm in average.