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Cs[Me 2 GaF 2 ], ein solvensfreies Caesiumsalz des einfachsten Diorganodifluorogallats
Author(s) -
Kopp Mike R.,
Neumüller Bernhard
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199809)624:9<1393::aid-zaac1393>3.0.co;2-7
Subject(s) - toluene , caesium , chemistry , salt (chemistry) , solvent , crystallography , nuclear chemistry , mineralogy , materials science , analytical chemistry (journal) , inorganic chemistry , organic chemistry
Cs[Me 2 GaF 2 ], a Solvent‐free Caesium Salt of the Plainest Diorganodifluoro Gallate The metalate Cs[Me 2 GaF 2 ] ( 1 ), obtained by the reaction of Cs[Me 3 GaF] with H 2 O in THF and recrystallized from toluene, was characterized by an X‐ray structure determination. According to the structure analysis, 1 consists of puckered layers of Cs[Me 2 GaF 2 ] stacked along [001].