The Structure of Hydrotris(pyrazolyl)boratothallium(I) | Zendy

Janiak Christoph | Zendy; Temizdemir Savaş | Zendy; Scharmann Tobias G. | Zendy

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The Structure of Hydrotris(pyrazolyl)boratothallium(I)

Author(s) -

Janiak Christoph,

Temizdemir Savaş,

Scharmann Tobias G.

Publication year - 1998

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/(sici)1521-3749(199805)624:5<755::aid-zaac755>3.0.co;2-j

Subject(s) - monoclinic crystal system , thallium , crystallography , molecule , group (periodic table) , metal , ligand (biochemistry) , chemistry , crystal structure , stereochemistry , materials science , inorganic chemistry , receptor , organic chemistry , biochemistry

The title compound crystallizes in the monoclinic space group P2 1 with a = 7.928(6), b = 9.306(4), c = 17.16(2) Å, β = 92.06(8)°, V = 1265(2) Å 3 , Z = 2, D calc = 2.191 g cm –3 . From two independent molecular units, metal‐ligand strands are formed based on electrostatic interactions between the thallium centers and pyrazolyl π manifolds from neighboring molecules.

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