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The Structure of Hydrotris(pyrazolyl)boratothallium(I)
Author(s) -
Janiak Christoph,
Temizdemir Savaş,
Scharmann Tobias G.
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199805)624:5<755::aid-zaac755>3.0.co;2-j
Subject(s) - monoclinic crystal system , thallium , crystallography , molecule , group (periodic table) , metal , ligand (biochemistry) , chemistry , crystal structure , stereochemistry , materials science , inorganic chemistry , receptor , organic chemistry , biochemistry
Abstract The title compound crystallizes in the monoclinic space group P2 1 with a = 7.928(6), b = 9.306(4), c = 17.16(2) Å, β = 92.06(8)°, V = 1265(2) Å 3 , Z = 2, D calc = 2.191 g cm –3 . From two independent molecular units, metal‐ligand strands are formed based on electrostatic interactions between the thallium centers and pyrazolyl π manifolds from neighboring molecules.