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Synthese, Eigenschaften und Struktur von [Li(OC 4 H 8 ) 4 ][((CH 3 ) 3 Si) 3 C–InBr 3 ]
Author(s) -
Walz A.,
Klinkhammer K. W.,
Weidlein J.
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199801)624:1<4::aid-zaac4>3.0.co;2-5
Subject(s) - raman spectroscopy , yield (engineering) , molar ratio , chemistry , materials science , organic chemistry , catalysis , physics , metallurgy , optics
Synthesis, Properties, and X‐Ray Structure Determination of [Li(OC 4 H 8 ) 4 ][((CH 3 ) 3 Si) 3 C–InBr 3 ] The reaction of InBr 3 with LiR* · (THF) n (R* = –C(SiMe 3 ) 3 , THF = OC 4 H 8 ) in a 1 : 1 molar ratio forms [Li(THF) 4 ][R*InBr 3 ] in good yield. The properties and some spectroscopic data ( 1 H, 13 C, 29 Si, 7 Li–NMR, IR and Raman) of this trisyl‐tribromoindate are given and the crystal structure has been determined.