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Br 3 In · NH 2 Si(CH 3 ) 3 – ein stabiles Addukt des instabilen Trimethylsilylamins
Author(s) -
Kühner S.,
Hausen H.D.,
Weidlein J.
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199801)624:1<13::aid-zaac13>3.0.co;2-m
Subject(s) - adduct , chemistry , raman spectroscopy , molar ratio , medicinal chemistry , tribromide , organic chemistry , catalysis , optics , physics
Br 3 In · NH 2 Si(CH 3 ) 3 – a Stable Adduct of the Unstable Trimethylsilylamine Heating a solution of indium tribromide in bis(trimethylsilyl)amine at about 55 °C for 30 to 35 hours the two adducts Br 3 In · NH 2 SiMe 3 and Br 3 In · NH(SiMe 3 ) 2 are formed in a 3 : 1 molar ratio. Both compounds have been characterized by NMR, IR and Raman spectra; the X‐ray structure determination of the title compound is reported.