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Synthese und Einkristallstrukturanalyse von Bis(benzyltrimethylammonium)fullerid‐Ammoniakat; (BzlNMe 3 ) 2 C 60 · 3 NH 3
Author(s) -
Himmel Klaus,
Jansen Martin
Publication year - 1998
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/(sici)1521-3749(199801)624:1<1::aid-zaac1>3.0.co;2-h
Subject(s) - ammonia , liquid ammonia , chemistry , potassium , ion , single crystal , ion exchange , fullerene , crystal structure , crystallography , layer (electronics) , inorganic chemistry , organic chemistry
Synthesis and Single Crystal Structure Analysis of Bis(benzyltrimethylammonium)fulleride Ammonia 1/3, (BzlNMe 3 ) 2 C 60 · 3 NH 3 The title compound has been prepared from K 2 C 60 by ion exchange of potassium for benzyltrimethylammonium cations in liquid ammonia. X‐ray single crystal structure analysis reveals highly ordered fulleride ions forming a layer‐like arrangement with short inter‐fullerene distances. The anionic fulleride layers are separated by layers of benzyltrimethylammonium cations and ammonia.