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Chiral separation of enantiomers via selector/selectand hydrogen bondings
Author(s) -
Feibush Binyamin
Publication year - 1998
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/(sici)1520-636x(1998)10:5<382::aid-chir4>3.0.co;2-8
Subject(s) - chemistry , diastereomer , enantiomer , chirality (physics) , hydrogen bond , elution , hydrogen , chromatographic separation , chromatography , crystallography , stereochemistry , organic chemistry , molecule , high performance liquid chromatography , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark
The progress made in the development of chiral stationary phases based on hydrogen‐bonding selector/selectand associates is reviewed here. The structure of the different selectand/selector systems was established through X‐ray diffraction and other spectroscopic techniques. The structure of the energetically more stable diastereomeric‐associate was then correlated to the chromatographic results, namely to the elution order and the enantioselectivity of each of the systems. Chirality 10:382–395, 1998. © 1998 Wiley‐Liss, Inc.