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Preparation of polyamino acid catalysts for use in Juliá asymmetric epoxidation
Author(s) -
Bentley P. A.,
Kroutil W.,
Littlechild J. A.,
Roberts S. M.
Publication year - 1997
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/(sici)1520-636x(1997)9:2<198::aid-chir22>3.0.co;2-h
Subject(s) - chemistry , chirality (physics) , catalysis , oligopeptide , combinatorial chemistry , enantioselective synthesis , stereochemistry , organic chemistry , polymer chemistry , peptide , biochemistry , physics , chiral symmetry breaking , quantum mechanics , nambu–jona lasinio model , quark
Abstract This article describes improvements in the Juliá asymmetric epoxidation reaction. The oligopeptides needed for the study were synthesised from N‐carboxyanhydrides (NCAs) employing various initiators, such as water, 1,3‐diaminopropane (DAP), and cross‐linked aminomethylpolystyrene (CLAMPS) 1. Chirality 9:198–202, 1997. © 1997 Wiley‐Liss, Inc.