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Benzoates of cellulose bonded on silica gel: Chiral discrimination ability as high‐performance liquid chromatographic chiral stationary phases
Author(s) -
Oliveros Laureano,
Senso Antonio,
Minguillón Cristina
Publication year - 1997
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/(sici)1520-636x(1997)9:2<145::aid-chir12>3.0.co;2-n
Subject(s) - chemistry , benzoates , silica gel , heptane , chromatography , cellulose , chirality (physics) , organic chemistry , chloroform , chiral column chromatography , high performance liquid chromatography , asymmetric carbon , optically active , chiral symmetry breaking , physics , quantum mechanics , nambu–jona lasinio model , quark
Abstract In order to generalize the recently described method for the insolubilization of polysaccharide derivatives to benzoates of cellulose, five mixed 10‐undecenoate/benzoates of this polysaccharide have been prepared and linked to allyl silica gel by means of a radical reaction. The chiral recognition ability of the resulting materials when used as high‐performance liquid chromatographic chiral stationary phases was evaluated using heptane/2‐propanol and heptane/chloroform mixtures as mobile phases. Chirality 9:145–149, 1997. © 1997 Wiley‐Liss, Inc.