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Chiroptical properties and conformation of chiral enamines of 2‐(2′‐pyrido, or quinolino) acetophenone
Author(s) -
Majer Zsuzsa,
Hollósi Miklos,
Kirin Srečko I.,
Šunjić Vitomir
Publication year - 1996
Publication title -
chirality
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.43
H-Index - 77
eISSN - 1520-636X
pISSN - 0899-0042
DOI - 10.1002/(sici)1520-636x(1996)8:3<244::aid-chir3>3.0.co;2-h
Subject(s) - chromophore , chemistry , exciton , acetophenone , stereochemistry , chirality (physics) , computational chemistry , photochemistry , organic chemistry , catalysis , chiral symmetry , physics , quantum mechanics , nambu–jona lasinio model , quark
CD study of the chiral enamines 4‐9 revealed the presence of the azastil‐bene‐like chromophore, and exciton coupling between this chromophore (A) and aromatic chromophore B . Coupled excitons in 5 and 8 suggest M (−) absolute conformation between chromophores A and B . © 1996 Wiley‐Liss, Inc.