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The crosslinking mechanism in gamma irradiation of polyarylsulfone: evidence for Y‐links
Author(s) -
Hill David J. T.,
Lewis David A.,
O'Donnell James H.,
Whittaker Andrew K.
Publication year - 1998
Publication title -
polymers for advanced technologies
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.61
H-Index - 90
eISSN - 1099-1581
pISSN - 1042-7147
DOI - 10.1002/(sici)1099-1581(199801)9:1<45::aid-pat733>3.0.co;2-s
Subject(s) - polysulfone , irradiation , materials science , gamma irradiation , polymer , spectral line , mechanism (biology) , polymer chemistry , chemistry , composite material , physics , quantum mechanics , nuclear physics , astronomy
Measurements of molecular weights, soluble fractions and examination of NMR spectra of bisphenol‐A polysulfone, after gamma irradiation in vacuum at 150°C were used to elucidate the mechanism of crosslinking. Excellent agreement was obtained between G(S) and G(X) determined from measurements above and below the gel dose when a Y‐linking mechanism was assumed, whereas poor agreement was obtained when an H‐link mechanism was assumed, which is the mechanism normally believed to be responsible for crosslinking. New resonances were observed in the 13 C NMR spectra of the irradiated polymer which were consistent with the formation of Y‐links involving phenylene units in the backbone chain. © 1998 John Wiley & Sons, Ltd.